The timing you're referring to is spark timing, and your cam should have been degreed when it was installed, especially if you milled the head as well. Basically after milling the head and the new cam, plus a cam gear, true TDC is now off from the timing marks and you need first to pull spark plug no.1 and drop a long screwdriver into the hole, then rotate the motor counter clockwise till you see the screwdriver begin to drop again, this will help you find true TDC on the crank, the second half is a little harder, even worse with the motor in the car, but you need a degree wheel of sorts and a dial gauge. You need to look up proper procedure for this, but basically you need to find TDC for the cam as well, then adjust the cam gear, sorta ignoring the numbers on it, to your new "0" position. This is your motors true TDC, then you can set your spark timing from there.
Also to consider is your distributor springs might be crapped out and not giving you the correct advance.